492 BY-PRODUCTS IN SULPHURIC ACID MANUFACTURE The cause of this plasticity when grinding might be that part of the iron oxide was in a colloidal state, and constantly retained water. Bird found that about 17 per cent moisture in the purple ore was necessary for briquetting (see infra). The discovery that roasted ore can be briquetted without any other binder than water is therefore due to Bird. Grondal and Dellvik found in 1896 that moistened ore dust from a stamp- mill could be pressed into briquettes, which after burning became very solid, showing that iron-ore acted in the same way as purple ore. Ram6nl states that the fundamental point of great im- portance which is often overlooked is the deleterious effect of the binder used in making the briquettes. The iron content of the ore being lowered, the cost of production per ton of metal is increased, whether the binder is of acid or neutral character. Attention has to be paid not only to the cost of the slagging of these binders, which is a matter of considerable importance, but also to the fact that the quantity of iron produced per unit weight of briquettes is reduced in a corresponding degree. In contrast with this, the cost of producing pig-iron from a briquette made without a binder entails a saving of coal, and gives a greater output, and the commercial aspects of the smelting operations are improved correspondingly. In Swedish furnaces using charcoal it has been proved that by smelting briquettes, which are easily reduced, an increased output and a considerable saving in fuel have resulted. With regard to blast-furnaces using coke, an experiment has recently been made at a German plant In this experiment 2000 tons of purple-ore briquettes from Helsingborg's copper plant were smelted with coke in a blast-furnace, and the experience gained by the Swedish furnaces was fully verified. This test showed a considerable reduction in the coke con- sumption as well as an increase in the output of pig-iron, also an increase of 25 to 30 per cent in the capacity of the furnace The saving in coke amounted to 8 per cent, and would be still higher in the case of a more regular operation during a longer period. When figuring the saving which accrues from smelting briquettes of good quality, as against smelting unbriquetted ore, 1 Lecture given at the meeting of the Verein Deutscher Eisenhutteleute, ist December 1912.